The central objective of this internship is to establish a reproducible route for fabricating europium molecular membranes and, crucially, to determine whether their exceptional optical properties are preserved after exfoliation and transfer. The student will optimize the mechanical exfoliation conditions to increase the yield of thin, large-area flakes; develop deterministic dry-transfer protocols onto photonic substrates such as SiC, SiO2/Si and glass; characterize membrane thickness, morphology and crystalline quality using optical interference microscopy, atomic force microscopy and Raman spectroscopy; and investigate their luminescence and optical homogeneous linewidths at cryogenic temperatures using spectral hole burning. Comparison with bulk crystals will allow the influence of exfoliation, reduced thickness and substrate coupling on the optical coherence of the molecular material to be established.

This internship will focus on measuring mid-infrared molecular transitions of methanol (CH3OH), ammonia (NH3), and other molecules known for their enhanced sensitivity to changes in µ. The work will involve achieving subDoppler spectroscopic resolution to reach target laboratory frequency accuracies of ~100 Hz needed for comparisons with astronomical observations. This activity is part of the ANR Ultiµos project, a collaborative effort which seeks to refine current constraints on the possible variation of µ which involves leading research institutions, including Laboratoire Kastler Brossel (LKB, L. Hilico) and MONARIS (C. Janssen) at Sorbonne Université. The three partners of the Ultiµos consortium will collaborate to conduct measurements in different spectral windows, to identify transitions as targets for future Earth/space comparison campaigns, which could further tighten constraints on variations of µ. Other collaborators, such as Vrije Universiteit Amsterdam and Onsala Space Observatory, will provide theoretical and observational/astronomical support to complement the experimental efforts.

The master student will join the effort at LPL to develop a new-generation compact and versatile microwave (MW) spectrometer operating over the 2–20 GHz range. This instrument is conceived both as a high-sensitivity detector of internal quantum states in polyatomic molecules and as a precision tool for molecular frequency metrology. The spectrometer will enable cross-checks between MW rotational frequencies and mid-infrared (MIR) rovibrational data planned to be measured at the 100 Hz level in the frame of the ANR Ultiµos project. These comparisons are directly motivated by the search for potential variations of the proton-to-electron mass ratio µ, a fundamental constant whose stability can be tested by confronting laboratory data with MW astronomical spectra of molecules such as methanol and ammonia. These species possess transitions with strong sensitivity coefficients to µ, making them powerful probes of possible temporal or spatial variations of fundamental constants. In Ultiµos, spectroscopy with ultrastable MIR quantum cascade lasers provide ultra-precise MIR frequencies with relative uncertainties of 10 ¹². By using combination–difference schemes, these MIR data yield effective MW intervals that can be directly confronted with our SI-traceable MW measurements. Such dual determinations, based on entirely different experimental chains and affected by distinct systematic effects, are ideal for robust cross-validation of frequency values and uncertainty budgets.

The goal of this internship is to develop and characterize nonlinear acousto-optic devices operating in the mid-infrared (wavelength of 3-8µm), leveraging broadband transparency and piezoelectricity of III-V semiconductor heterostructures. These devices will perform phase modulation, but also potentially on-chip optical routing, a pre-requisite for magnetic field-free optical isolation. The internship will be mostly experimental, involving the use and development of two existing setups. The first one is a mid-IR integrated photonic bench allowing to characterize the operation of the devices (see above, right). The second one is a heterodyne interferometer, that allows to image the SAW-related vibration (amplitude and phase) of the sample surface to characterize the acoustic properties of the devices (see above, left).